ΔrH° |
|
kJ/mol |
PDiss |
Tecklenberg, Bricker, et al.,H2O = (Fe+ • 2H2O)
Cantidad |
Valor |
Unidades |
Método |
Referencia |
Comentario |
ΔrH° |
|
kJ/mol |
CID |
Marinelli y Squires, 1989 |
fase de gas; M |
la Entalpía de la reacción
ΔrH° (kJ/mol) |
T (K) |
Método |
Referencia |
Comentario |
164., (+4.2,-0.,/td>
| CID |
Armentrout and Kickel, 1994 |
gas phase; guided ion beam CID; M |
( • 2) + = ( • 3)
By formula: (Fe+ • 2CO) + CO = (Fe+ • 3CO)
Quantity |
Value |
Units |
Method |
Reference |
Comment |
ΔrH° |
69.,0 ± 5.9 |
kJ/mol |
CIDT |
Rodgers and Armentrout, 2000 |
RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) |
T (K) |
Method |
Reference |
Comment |
66.1 (+5.0,-0.,/td>
| CID |
Armentrout and Kickel, 1994 |
gas phase; guided ion beam CID; M |
( • 3) + = ( • 4)
By formula: (Fe+ • 3CO) + CO = (Fe+ • 4CO)
Quantity |
Value |
Units |
Method |
Reference |
Comment |
ΔrH° |
97.,9 ± 5.9 |
kJ/mol |
CIDT |
Rodgers and Armentrout, 2000 |
RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) |
T (K) |
Method |
Reference |
Comment |
103. (+7.1,-0.,/td>
| CID |
Armentrout and Kickel, 1994 |
gas phase; guided ion beam CID; M |
( • 4) + = ( • 5)
By formula: (Fe+ • 4CO) + CO = (Fe+ • 5CO)
Quantity |
Value |
Units |
Method |
Reference |
Comment |
ΔrH° |
97.,1 ± 4.2 |
kJ/mol |
CIDT |
Rodgers and Armentrout, 2000 |
RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) |
T (K) |
Method |
Reference |
Comment |
112. (+4.2,-0., |
CID |
Armentrout and Kickel, 1994 |
gas phase; guided ion beam CID; M |
( • ) + = ( • 2)
By formula: (Fe+ • CO) + CO = (Fe+ • 2CO)
Quantity |
Value |
Units |
Method |
Reference |
Comment |
ΔrH° |
148., ± 5.0 |
kJ/mol |
CIDT |
Rodgers and Armentrout, 2000 |
RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) |
T (K) |
Method |
Reference |
Comment |
151. (+14.,-0.,
| CID |
Armentrout and Kickel, 1994 |
gas phase; guided ion beam CID; M |
( • ) + = ( • 2)
By formula: (Fe+ • C6H6) + C6H6 = (Fe+ • 2C6H6)
Quantity |
Value |
Units |
Method |
Reference |
Comment |
ΔrH° |
187., ± 16. |
kJ/mol |
CIDT |
Meyer, Khan, et al., 1995 |
RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) |
T (K) |
Method |
Reference |
Comment |
187. (+16.,-0.) |
|
CID |
Meyer, Khan, et al., phase; guided ion beam CID; M |
+ = ( • )
By formula: Fe+ + CH3 = (Fe+ • CH3)
+ = ( • )
By formula: Fe+ + C2H6 = (Fe+ • C2H6)
Quantity |
Value |
Units |
Method |
Reference |
Comment |
ΔrH° |
70., ± 10. |
kJ/mol |
MKER |
Carpenter, van Koppen, et al., 1995 |
gas phase; M |
Enthalpy of reaction
ΔrH° (kJ/mol) |
T (K) |
Method |
Reference |
Comment |
64.0 (+5.9,-0.,
gas phase; guided ion beam CID; M |
( • 2) + = ( • 3)
By formula: (Fe+ • 2Fe) + Fe = (Fe+ • 3Fe)
Quantity |
Value |
Units |
Method |
Reference |
Comment |
ΔrH° |
|
kJ/mol |
CID |
Loh, Lian, et al.,mment
|
|
|
CID |
Armentrout and Kickel, 1994 |
gas phase; guided ion beam CID; M |
+ = ( • )
By formula: Fe+ + C2H4 = (Fe+ • C2H4)
Quantity |
Value |
Units |
Method |
Reference |
Comment |
ΔrH° |
145., ± 11. |
kJ/mol |
CIDT |
Sievers, Jarvis, et al., 1998 |
RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) |
T (K) |
Method |
Reference |
Comment |
145. (+5.9,-0.,d>
| CID |
Armentrout and Kickel, 1994 |
gas phase; guided ion beam CID; M |
( • ) + = ( • 2)
By formula: (Fe+ • H3N) + H3N = (Fe+ • 2H3N)
Quantity |
Value |
Units |
Method |
Reference |
Comment |
ΔrH° |
225., ± 12.,>
ΔrH° |
|
kJ/mol |
CID |
Marinelli and Squires, 1989 |
gas phase; M |
+ = ( • )
By formula: Fe+ + H3N = (Fe+ • H3N)
Quantity |
Value |
Units |
Method |
Reference |
Comment |
ΔrH° |
183., ± 12.,c»>
ΔrH° |
|
kJ/mol |
CID |
Marinelli and Squires, 1989 |
gas phase; M |
+ = ( • )
By formula: Fe+ + CS = (Fe+ • CS)
Quantity |
Value |
Units |
Method |
Reference |
Comment |
ΔrH° |
207., ± 13. |
kJ/mol |
CIDT |
Rodgers and Armentrout, 2000 |
RCD |
ΔrH° |
231. ± 12. |
kJ/mol |
CIDT |
Schroeder, Kretzschmar, et al.,, 1999 |
RCD |
( • 2) + = ( • 3)
By formula: (Fe+ • 2H2O) + H2O = (Fe+ • 3H2O)
Enthalpy of reaction
ΔrH° (kJ/mol) |
T (K) |
Method |
Reference |
Comment |
76.1 (+4.2,-0.,) |
|
CID |
Armentrout and Kickel, 1994 |
gas phase; guided ion beam CID; M |
( • 3) + = ( • 4)
By formula: (Fe+ • 3H2O) + H2O = (Fe+ • 4H2O)
Enthalpy of reaction
ΔrH° (kJ/mol) |
T (K) |
Method |
Reference |
Comment |
82.,0 (+7.1,-0.,v id=»7f82ff5168″>
• 3 • 2) + = ( • 4 • 2)
By formula: (Fe+ • 3CO • 2Fe) + CO = (Fe+ • 4CO • 2Fe)
Quantity |
Value |
Units |
Method |
Reference |
Comment |
ΔrH° |
|
kJ/mol |
PDiss |
Tecklenberg, Bricker, et al.,, 1988 |
gas phase; ΔrH<; M |
( • 2) + = ( • 3)
By formula: (Fe+ • 2CH4) + CH4 = (Fe+ • 3CH4)
Enthalpy of reaction
ΔrH° (kJ/mol) |
T (K) |
Method |
Reference |
Comment |
99.2 (+5.9,-0.,) |
|
CID |
Armentrout and Kickel, 1994 |
gas phase; guided ion beam CID; M |
( • 3) + = ( • 4)
By formula: (Fe+ • 3CH4) + CH4 = (Fe+ • 4CH4)
Enthalpy of reaction
ΔrH° (kJ/mol) |
T (K) |
Method |
Reference |
Comment |
74.,1 (+5.9,-0.,) |
|
CID |
Armentrout and Kickel, 1994 |
gas phase; guided ion beam CID; M |
( • ) + = ( • 2)
By formula: (Fe+ • CH4) + CH4 = (Fe+ • 2CH4)
Enthalpy of reaction
ΔrH° (kJ/mol) |
T (K) |
Method |
Reference |
Comment |
97.,1 (+4.2,-0.,> |
( • ) + = ( • • )
By formula: (Fe+ • Fe) + CO = (Fe+ • CO • Fe)
Quantity |
Value |
Units |
Method |
Reference |
Comment |
ΔrH° |
|
kJ/mol |
PDiss |
Tecklenberg, Bricker, et al.,, 1988 |
gas phase; ΔrH<; M |
+ = ( • )
By formula: Fe+ + C3H6 = (Fe+ • C3H6)
Enthalpy of reaction
ΔrH° (kJ/mol) |
T (K) |
Method |
Reference |
Comment |
145. (+7.1,-0.,) |
|
CID |
Armentrout and Kickel, 1994 |
gas phase; guided ion beam CID; M |
+ = ( • )
By formula: Fe+ + CH4 = (Fe+ • CH4)
Enthalpy of reaction
ΔrH° (kJ/mol) |
T (K) |
Method |
Reference |
Comment |
57. (+3.,-0.,) |
|
CID |
Armentrout and Kickel, 1994 |
gas phase; guided ion beam CID; M |
+ = ( • )
By formula: Fe+ + C3H8 = (Fe+ • C3H8)
Enthalpy of reaction
ΔrH° (kJ/mol) |
T (K) |
Method |
Reference |
Comment |
74.9 (+4.2,-0.,>
| CID |
Armentrout and Kickel, 1994 |
gas phase; guided ion beam CID; M |
( • 2) + = ( • 3)
By formula: (Fe+ • 2H3N) + H3N = (Fe+ • 3H3N)
Quantity |
Value |
Units |
Method |
Reference |
Comment |
ΔrH° |
68., ± 13. |
kJ/mol |
CIDT |
Walter and Armentrout, 1998 |
RCD |
ir a: arriba, datos de termoquímica de reacción, notas
derechos de autor de compilación de datos por el Secretario de comercio de los EE., utilizado en este documento:
t |
temperatura |
ΔrH° |
entalpía de reacción en condiciones estándar |
ΔrS° |
entropía de reacción en condiciones estándar |
<31c6a31997">
data from NIST standard reference database 69:NIST chemistry Webbook
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