ΔrH° |
|
kJ/mol |
PDiss |
Tecklenberg, Bricker, et al.,H2O = (Fe+ • 2H2O)
Cantitate |
Valoare |
Unități |
Metoda |
de Referință |
Comentariu |
ΔrH° |
|
kJ/mol |
CID |
Marinelli și Squires, 1989 |
fază gazoasă; M |
Entalpia de reacție
ΔrH° (kJ/mol) |
T (K) |
Metoda |
de Referință |
Comentariu |
164., (+4.2,-0.,/td>
| CID |
Armentrout and Kickel, 1994 |
gas phase; guided ion beam CID; M |
( • 2) + = ( • 3)
By formula: (Fe+ • 2CO) + CO = (Fe+ • 3CO)
Quantity |
Value |
Units |
Method |
Reference |
Comment |
ΔrH° |
69.,0 ± 5.9 |
kJ/mol |
CIDT |
Rodgers and Armentrout, 2000 |
RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) |
T (K) |
Method |
Reference |
Comment |
66.1 (+5.0,-0.,/td>
| CID |
Armentrout and Kickel, 1994 |
gas phase; guided ion beam CID; M |
( • 3) + = ( • 4)
By formula: (Fe+ • 3CO) + CO = (Fe+ • 4CO)
Quantity |
Value |
Units |
Method |
Reference |
Comment |
ΔrH° |
97.,9 ± 5.9 |
kJ/mol |
CIDT |
Rodgers and Armentrout, 2000 |
RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) |
T (K) |
Method |
Reference |
Comment |
103. (+7.1,-0.,/td>
| CID |
Armentrout and Kickel, 1994 |
gas phase; guided ion beam CID; M |
( • 4) + = ( • 5)
By formula: (Fe+ • 4CO) + CO = (Fe+ • 5CO)
Quantity |
Value |
Units |
Method |
Reference |
Comment |
ΔrH° |
97.,1 ± 4.2 |
kJ/mol |
CIDT |
Rodgers and Armentrout, 2000 |
RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) |
T (K) |
Method |
Reference |
Comment |
112. (+4.2,-0., |
CID |
Armentrout and Kickel, 1994 |
gas phase; guided ion beam CID; M |
( • ) + = ( • 2)
By formula: (Fe+ • CO) + CO = (Fe+ • 2CO)
Quantity |
Value |
Units |
Method |
Reference |
Comment |
ΔrH° |
148., ± 5.0 |
kJ/mol |
CIDT |
Rodgers and Armentrout, 2000 |
RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) |
T (K) |
Method |
Reference |
Comment |
151. (+14.,-0.,
| CID |
Armentrout and Kickel, 1994 |
gas phase; guided ion beam CID; M |
( • ) + = ( • 2)
By formula: (Fe+ • C6H6) + C6H6 = (Fe+ • 2C6H6)
Quantity |
Value |
Units |
Method |
Reference |
Comment |
ΔrH° |
187., ± 16. |
kJ/mol |
CIDT |
Meyer, Khan, et al., 1995 |
RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) |
T (K) |
Method |
Reference |
Comment |
187. (+16.,-0.) |
|
CID |
Meyer, Khan, et al., phase; guided ion beam CID; M |
+ = ( • )
By formula: Fe+ + CH3 = (Fe+ • CH3)
+ = ( • )
By formula: Fe+ + C2H6 = (Fe+ • C2H6)
Quantity |
Value |
Units |
Method |
Reference |
Comment |
ΔrH° |
70., ± 10. |
kJ/mol |
MKER |
Carpenter, van Koppen, et al., 1995 |
gas phase; M |
Enthalpy of reaction
ΔrH° (kJ/mol) |
T (K) |
Method |
Reference |
Comment |
64.0 (+5.9,-0.,
gas phase; guided ion beam CID; M |
( • 2) + = ( • 3)
By formula: (Fe+ • 2Fe) + Fe = (Fe+ • 3Fe)
Quantity |
Value |
Units |
Method |
Reference |
Comment |
ΔrH° |
|
kJ/mol |
CID |
Loh, Lian, et al.,mment
|
|
|
CID |
Armentrout and Kickel, 1994 |
gas phase; guided ion beam CID; M |
+ = ( • )
By formula: Fe+ + C2H4 = (Fe+ • C2H4)
Quantity |
Value |
Units |
Method |
Reference |
Comment |
ΔrH° |
145., ± 11. |
kJ/mol |
CIDT |
Sievers, Jarvis, et al., 1998 |
RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) |
T (K) |
Method |
Reference |
Comment |
145. (+5.9,-0.,d>
| CID |
Armentrout and Kickel, 1994 |
gas phase; guided ion beam CID; M |
( • ) + = ( • 2)
By formula: (Fe+ • H3N) + H3N = (Fe+ • 2H3N)
Quantity |
Value |
Units |
Method |
Reference |
Comment |
ΔrH° |
225., ± 12.,>
ΔrH° |
|
kJ/mol |
CID |
Marinelli and Squires, 1989 |
gas phase; M |
+ = ( • )
By formula: Fe+ + H3N = (Fe+ • H3N)
Quantity |
Value |
Units |
Method |
Reference |
Comment |
ΔrH° |
183., ± 12.,c”>
ΔrH° |
|
kJ/mol |
CID |
Marinelli and Squires, 1989 |
gas phase; M |
+ = ( • )
By formula: Fe+ + CS = (Fe+ • CS)
Quantity |
Value |
Units |
Method |
Reference |
Comment |
ΔrH° |
207., ± 13. |
kJ/mol |
CIDT |
Rodgers and Armentrout, 2000 |
RCD |
ΔrH° |
231. ± 12. |
kJ/mol |
CIDT |
Schroeder, Kretzschmar, et al.,, 1999 |
RCD |
( • 2) + = ( • 3)
By formula: (Fe+ • 2H2O) + H2O = (Fe+ • 3H2O)
Enthalpy of reaction
ΔrH° (kJ/mol) |
T (K) |
Method |
Reference |
Comment |
76.1 (+4.2,-0.,) |
|
CID |
Armentrout and Kickel, 1994 |
gas phase; guided ion beam CID; M |
( • 3) + = ( • 4)
By formula: (Fe+ • 3H2O) + H2O = (Fe+ • 4H2O)
Enthalpy of reaction
ΔrH° (kJ/mol) |
T (K) |
Method |
Reference |
Comment |
82.,0 (+7.1,-0.,v id=”7f82ff5168″>
• 3 • 2) + = ( • 4 • 2)
By formula: (Fe+ • 3CO • 2Fe) + CO = (Fe+ • 4CO • 2Fe)
Quantity |
Value |
Units |
Method |
Reference |
Comment |
ΔrH° |
|
kJ/mol |
PDiss |
Tecklenberg, Bricker, et al.,, 1988 |
gas phase; ΔrH<; M |
( • 2) + = ( • 3)
By formula: (Fe+ • 2CH4) + CH4 = (Fe+ • 3CH4)
Enthalpy of reaction
ΔrH° (kJ/mol) |
T (K) |
Method |
Reference |
Comment |
99.2 (+5.9,-0.,) |
|
CID |
Armentrout and Kickel, 1994 |
gas phase; guided ion beam CID; M |
( • 3) + = ( • 4)
By formula: (Fe+ • 3CH4) + CH4 = (Fe+ • 4CH4)
Enthalpy of reaction
ΔrH° (kJ/mol) |
T (K) |
Method |
Reference |
Comment |
74.,1 (+5.9,-0.,) |
|
CID |
Armentrout and Kickel, 1994 |
gas phase; guided ion beam CID; M |
( • ) + = ( • 2)
By formula: (Fe+ • CH4) + CH4 = (Fe+ • 2CH4)
Enthalpy of reaction
ΔrH° (kJ/mol) |
T (K) |
Method |
Reference |
Comment |
97.,1 (+4.2,-0.,> |
( • ) + = ( • • )
By formula: (Fe+ • Fe) + CO = (Fe+ • CO • Fe)
Quantity |
Value |
Units |
Method |
Reference |
Comment |
ΔrH° |
|
kJ/mol |
PDiss |
Tecklenberg, Bricker, et al.,, 1988 |
gas phase; ΔrH<; M |
+ = ( • )
By formula: Fe+ + C3H6 = (Fe+ • C3H6)
Enthalpy of reaction
ΔrH° (kJ/mol) |
T (K) |
Method |
Reference |
Comment |
145. (+7.1,-0.,) |
|
CID |
Armentrout and Kickel, 1994 |
gas phase; guided ion beam CID; M |
+ = ( • )
By formula: Fe+ + CH4 = (Fe+ • CH4)
Enthalpy of reaction
ΔrH° (kJ/mol) |
T (K) |
Method |
Reference |
Comment |
57. (+3.,-0.,) |
|
CID |
Armentrout and Kickel, 1994 |
gas phase; guided ion beam CID; M |
+ = ( • )
By formula: Fe+ + C3H8 = (Fe+ • C3H8)
Enthalpy of reaction
ΔrH° (kJ/mol) |
T (K) |
Method |
Reference |
Comment |
74.9 (+4.2,-0.,>
| CID |
Armentrout and Kickel, 1994 |
gas phase; guided ion beam CID; M |
( • 2) + = ( • 3)
By formula: (Fe+ • 2H3N) + H3N = (Fe+ • 3H3N)
Quantity |
Value |
Units |
Method |
Reference |
Comment |
ΔrH° |
68., ± 13. |
kJ/mol |
CIDT |
Walter și Armentrout, 1998 |
RCD |
Du-te La: De sus, de Reacție thermochemistry de date, Note
compilare a Datelor copyrightby Secretarul AMERICAN de Comerț în numele U. S. A. Toate drepturile rezervate., utilizate în acest document:
T |
Temperatura |
ΔrH° |
Entalpia de reacție, în condiții standard |
ΔrS° |
Entropia de reacție în condiții standard |
Date de la NIST Standard de Date de Referință 69:NIST Chimie WebBook
Institutul Național de Standarde și Tehnologie (NIST)utilizează eforturile pentru a furniza o copie de înaltă calitate din baza de date și pentru a verifica dacă datele conținute de acestea au fost selectate pe baza de sunet judecată științifică.,Cu toate acestea, NIST nu oferă nicio garanție în acest sens și NISTshall nu este răspunzător pentru niciun prejudiciu care ar putea rezulta dinerori sau omisiuni în baza de date.
suport pentru Cliențipentru produsele de date de referință standard NIST.
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